Colin Youngs gives a good daily roundup of the maxima on uk.sci.weather. I'm not sure where he gets the maxima for the stations that aren't on the Ogimet synop roundup so it's the only place they seem to be publicly available.
Pasting them in here for the data nerds:
Thursday 6 August:
Farnborough and Manston 28.0°C, Herstmonceux 28.2°C, Goudhurst (Kent) 28.7°C, East Malling 28.8°C, Frittenden (Kent) 29.1°C, Chertsey 29.3°C, London St James’s Park 29.5°C, Northolt and Heathrow 29.7°C, Kew Gardens 29.9°C, Wisley 30.1°C.
Friday 7 August:
Benson 34.5°C, Odiham 34.6°C, Reading University 35.0°C, Farnborough 35.2°C, Santon Downham 35.3°C, Teddington 35.8°C, Slough (Cippenham Water Works) 35.9°C, Wisley, Northolt and London St James’s Park 36.1°C, Chertsey 36.2°C, Heathrow and Kew Gardens 36.4°C.
Saturday 8 August:
Bournemouth (Hurn) 32.9°C, Wych Cross (East Sussex) and Langdon Bay 33.0°C, Thorney Island 33.1°C, London St James’s Park 33.2°C, Heathrow 33.4°C, Writtle (Essex) 33.5°C, Gosport 33.8°C, Goudhurst (Kent) 34.4°C, Wiggonholt (West Sussex), Herstmonceux and Frittenden (Kent) 34.5°C.
Sunday 9 August:
Teddington 32.7°C, Farnborough, Wisley and Farnham (Alice Holt Lodge) 32.8°C, Slough (Cippenham Water Works) 32.9°C, Thorney Island 33.1°C, Shoreham 33.2°C, Northolt and Kew Gardens 33.5°C, Gosport and Heathrow 33.8°C, Wiggonholt (West Sussex) 33.9°C, Herstmonceux 34.0°C.
Monday 10 August:
TBC
And may as well add this in:
Friday 31 July:
Brize Norton and Farnborough 35.4°C, Bedford 35.9°C, Wellesbourne (Warks) and Wisley 36.2°C, Benson and Chertsey 36.6°C, Teddington and London St James’s Park 36.7°C, Northolt 36.8°C, Kew Gardens 37.3°C, Heathrow 37.8°C.
Originally Posted by: Rob K